1456812-40-0Relevant articles and documents
Polyaminoborane main chain scission using N-heterocyclic carbenes; Formation of donor-stabilised monomeric aminoboranes
Stubbs, Naomi E.,Jurca, Titel,Leitao, Erin M.,Woodall, Christopher H.,Manners, Ian
supporting information, p. 9098 - 9100 (2013/09/24)
The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH-BH 2]n or [NH2-BH2]n at 20 °C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts, RNH-BH2-NHC (R = Me or H); a similar NHC adduct of Ph2NBCl2 was characterized by single crystal X-ray diffraction.