14581-80-7Relevant articles and documents
Copper-Catalyzed Anomeric O-Arylation of Carbohydrate Derivatives at Room Temperature
Verdelet, Tristan,Benmahdjoub, Sara,Benmerad, Belkacem,Alami, Mouad,Messaoudi, Samir
, p. 9226 - 9238 (2019/08/12)
Direct and practical anomeric O-arylation of sugar lactols with substituted arylboronic acids has been established. Using copper catalysis at room temperature under an air atmosphere, the protocol proved to be general, and a variety of aryl O-glycosides have been prepared in good to excellent yields. Furthermore, this approach was extended successfully to unprotected carbohydrates, including α-mannose, and it was demonstrated here how the interaction between carbohydrates and boronic acids can be combined with copper catalysis to achieve selective anomeric O-arylation.
Practical β-stereoselective O-glycosylation of phenols with penta-O-acetyl-β-D-glucopyranose
Lee, Yeon Soo,Rho, Eun Suk,Min, Yong Ki,Kim, Bum Tae,Kim, Ki Ho
, p. 503 - 506 (2007/10/03)
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Regioselective Bromination of O-β-Glycosylated Aromatics
Mabic, Stephane,Lepoittevin, Jean-Pierre
, p. 1705 - 1708 (2007/10/02)
The quasi quantitative and regioselective bromination of O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)phenols is described.The orientating effect of the glycoside group is compared with those of other oxygenated groups and its usefulness illustrated with