14606-38-3

Basic information

• Product Name: bis-(α-phenyliminobenzyl) sulfide
• Synonyms: bis-(α-phenyliminobenzyl) sulfide
• CAS NO: 14606-38-3
• Molecular Weight: 392.524
• Mol File: 14606-38-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: bis-(α-phenyliminobenzyl) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: bis-(α-phenyliminobenzyl) sulfide(14606-38-3)
• EPA Substance Registry System: bis-(α-phenyliminobenzyl) sulfide(14606-38-3)

Safety Data

• Hazardous Substances Data: 14606-38-3(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 636-04-4 N-Phenylbenzothioamide 
• 67-66-3 chloroform 
• 2556-46-9 N,N'-diphenylbenzamidine 
• 3335-22-6 thiobenzoyl chloride 
• 33345-17-4 N,N-diphenylbenzamidine 
• 60-29-7 diethyl ether 
• 98-09-9 benzenesulfonyl chloride 
• 71-43-2 benzene 
• 59754-70-0 Triethylammonium-N-pyrid-3-yl-dithiocarbamate 
• 52421-65-5 N,N-dimethyl-N'-thiobenzoylformamidine 
• 38430-03-4 N-phenylbenzimidoyl chloride 
• 4903-36-0 N-phenyl-benzimidoyl chloride 
• 7791-25-5 sulfuryl dichloride 

Downstream Products

• 93-98-1 N-phenyl benzoyl amide 
• 636-04-4 N-Phenylbenzothioamide 
• 5962-54-9 bis-(N-phenyl-benzimidoyl)-disulfane 

Relevant articles and documents

Pyridylisothiocyanate

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Reaction of N,N-Dimethyl-N'-thiobenzoylformamidine and N,N-Dimethyl-N'-phenylthiocarbamoylformamidine with N-Arylbenzimidoyl Chlorides

The reactions of N,N-dimethyl-N'-thiobenzoylformamidine (1) and N,N-dimethyl-N'-phenylthiocarbamoylformamidine (4) with N-arylbenzimidoyl chlorides (2) have been studied.Compound 1 reacts with 2 in dry chloroform at room temperature to give dimidoyl sulphides (3) in good yields.However, the reaction of 2 with 4 in dry tetrahydrofuran under reflux results in the formation of a mixture of thiobenzanilides (5) and N-aryl-N'-phenylbenzamidines (6).Possible mechanistic pathways for these reactions have been suggested.

Acid-catalysed Rearrangement of Bis-5,6-Dihydro-4H-1,3-thiazin-2-yl and Other Disulphides and Related Reactions

Some dithiocarbamates, thiocarbamates, and thiourea derivatives have been oxidised to the disulphides 1X(R2N=)C>2S2 with iodine.In the presence of trifluoroacetic acid, these lost sulphur giving the thiocarbonyl derivatives R1X(R2N=)C-N(R2)CSR1 (R1, R2, X =3, S; 2, S; Me, Me, S; Et, PhCH2, O; 5α-cholestan-3β-yl, Et, O; and Me, Ph, NMe).These rearrangements were most plausibly intramolecular, but proceeded by varying extents of intermolecular scrambling.