146073-70-3Relevant articles and documents
NUCLEOPHILIC RADICAL SUBSTITUTION OF POLYCHLOROAZINES
Kanomata, Nobuhiro,Igarashi, Mamoru,Tada, Masaru
, p. 1127 - 1138 (2007/10/02)
Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals.In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl.However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution.The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.