14629-62-0

Basic information

• Product Name: Phenethyl(triethylsilyl) ether
• Synonyms: (Triethylsilyl)phenethyl ether;Phenethyl(triethylsilyl) ether;Phenethyloxytriethylsilane;Triethylphenethyloxysilane
• CAS NO: 14629-62-0
• Molecular Formula: C₁₄H₂₄OSi
• Molecular Weight: 236.43
• Mol File: 14629-62-0.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 279.5±19.0 °C(Predicted)
• Appearance: /
• Density: 0.897±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Phenethyl(triethylsilyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: Phenethyl(triethylsilyl) ether(14629-62-0)
• EPA Substance Registry System: Phenethyl(triethylsilyl) ether(14629-62-0)

Safety Data

• Hazardous Substances Data: 14629-62-0(Hazardous Substances Data)

Upstream product

• 994-30-9 triethylsilyl chloride 
• 60-12-8 2-phenylethanol 
• 89597-33-1 (E)-1-methoxy-1-(triethylsiloxy)propene 
• 617-86-7 triethylsilane 
• 122-78-1 phenylacetaldehyde 
• 96-09-3 styrene oxide 
• 55453-17-3 triethyl((1-methoxy-2-methylprop-1-en-1-yl)oxy)silane 
• 101-97-3 Ethyl 2-phenylethanoate 
• 1112-54-5 vinyltriethylsilane 
• 4249-72-3 2-phenoxy-1-phenylethanol 
• 18296-01-0 triethylsilyl formate 
• 18406-24-1 1-(triethylsilyloxy)-4-methoxybenzene 
• 3558-60-9 1-methoxy-2-phenylethane 

Downstream Products

• 103-45-7 acetic acid phenethyl ester 
• 100-41-4 ethylbenzene 
• 1861-04-7 2-deuterioethylbenzene 
• 60-12-8 2-phenylethanol 

Relevant articles and documents

Mechanism of the dehydrogenative silylation of alcohols catalyzed by cationic gold complexes: An experimental and theoretical study

The catalytic activity both of cationic [(XDPP)Au][X] (XDPP=bis-2,5- diphenylphosphole xantphos X=BF4) and of the isolated gold hydride complex [(XDPP)2Au2H][OTf] in the dehydrogenative silylation process is presented. A p

Cationic Dirhodium Complexes Bridged by 2-Phosphinopyridines Having an Exquisitely Positioned Axial Shielding Group: A Molecular Design for Enhancing the Catalytic Activity of the Dirhodium Core

This report describes a strategy to create highly electrophilic dirhodium catalysts. The electrophilicity of lantern-Type dirhodium complexes is generally decreased by the coordination of a ligand to the axial site, which often causes a reduction in the catalytic activity. We designed and synthesized a series of cationic dirhodium complexes bridged by 2-diarylphosphinopyridines having a bulky 2,4,6-Triisopropylphenyl (Tip) group that can prevent the attack of external molecules to the closest axial site. Theoretical calculations indicated that the Tip group weakly interacts with the axial site but hardly reduces the electrophilicity of the dirhodium core. The complexes served as excellent catalyst precursors for the dehydrogenative silylation of alcohols using hydrosilanes under mild conditions and a low metal loading, producing the silyl ethers in higher yields in comparison to conventional dirhodium complexes.

Hydrosilylation of Carbonyls Catalyzed by Hydridoborenium Borate Salts: Lewis Acid Activation and Anion Mediated Pathways

The electronically unsaturated three-coordinated hydridoborenium cations [LBH]+[HB(C6F5)3]-(1) and [LBH]+[B(C6F5)4]-(2), supported by a bis(phosphinimino)amide ligand, were found to be excellent catalysts for hydrosilylation of a range of aliphatic and ar