14644-80-5 Usage
Description
(4-chlorocyclohex-1-yliumyl)[tris(4-chlorophenyl)]borate(1-), with the chemical formula [B(C6H4-4-Cl)3(C6H10-4-Cl)]-, is an organoboron compound that features a cyclohexyl cation and a tris(4-chlorophenyl)borate anion. This unique structure endows it with special properties, making it a valuable asset in the fields of organic chemistry, chemical research, materials science, and pharmaceuticals.
Uses
Used in Organic Synthesis:
(4-chlorocyclohex-1-yliumyl)[tris(4-chlorophenyl)]borate(1-) is used as a catalyst in the field of organic synthesis. Its unique structure and properties allow it to facilitate various chemical reactions, enhancing the efficiency and selectivity of the processes.
Used in Chemical Research:
In the realm of chemical research, (4-chlorocyclohex-1-yliumyl)[tris(4-chlorophenyl)]borate(1-) serves as a valuable tool for studying and understanding complex chemical reactions and mechanisms. Its application contributes to the advancement of knowledge in this scientific discipline.
Used in Materials Science:
(4-chlorocyclohex-1-yliumyl)[tris(4-chlorophenyl)]borate(1-) has been explored for potential applications in materials science. Its unique properties may contribute to the development of new materials with specific characteristics, such as improved stability, reactivity, or selectivity.
Used in Pharmaceuticals:
(4-chlorocyclohex-1-yliumyl)[tris(4-chlorophenyl)]borate(1-) has also been studied for its potential applications in the pharmaceutical industry. Its unique structure and properties may offer new opportunities for the development of novel drugs or drug delivery systems, potentially leading to more effective treatments for various medical conditions.
Check Digit Verification of cas no
The CAS Registry Mumber 14644-80-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,6,4 and 4 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 14644-80:
(7*1)+(6*4)+(5*6)+(4*4)+(3*4)+(2*8)+(1*0)=105
105 % 10 = 5
So 14644-80-5 is a valid CAS Registry Number.
14644-80-5Relevant articles and documents
Cassaretto, F. P.,McLafferty, J. J.,Moore, C. E.
, p. 376 - 380 (1965)
Palladium-Assisted "Aromatic Metamorphosis" of Dibenzothiophenes into Triphenylenes
Vasu, Dhananjayan,Yorimitsu, Hideki,Osuka, Atsuhiro
supporting information, p. 7162 - 7166 (2015/06/08)
Abstract Two new palladium-catalyzed reactions of aromatic sulfur compounds enabled the conversion of dibenzothiophenes into triphenylenes in four steps. This transformation of one aromatic framework into another consists of 1) 4-chlorobutylation of the dibenzothiophene to form the corresponding sulfonium salt, 2) palladium-catalyzed arylative ring opening of the sulfonium salt with a sodium tetraarylborate, 3) an intramolecular SN2 reaction to form a teraryl sulfonium salt, and 4) palladium-catalyzed intramolecular C-S/C-H coupling through electrophilic palladation. Symmetrical as well as unsymmetrical triphenylenes of interest were synthesized in a tailor-made fashion in satisfactory overall yields. A change of heart: The invention of two palladium-catalyzed arylation reactions of organosulfur compounds enabled the transformation of dibenzothiophenes into triphenylenes and thus a fundamental change in the core aromatic structure (see scheme). Both symmetrical and unsymmetrical triphenylenes were synthesized in a tailor-made fashion in satisfactory overall yield.
Rhodium-Catalyzed asymmetric synthesis of spirocarbocycles: arylboron reagents as surrogates of 1,2-dimetalloarenes
Shintani, Ryo,Isobe, Shingo,Takeda, Momotaro,Hayashi, Tamio
experimental part, p. 3795 - 3798 (2010/08/20)
(Figure Presented) Revolutionary Rh-oad: A rhodium/dienecatalyzed addition of sodium tetraarylborates to alkyne-tethered 2-cydoalken-lones has been developed for the synthesis of splrocarbocycles. The tetraarylborates catalytlcally form two new carbon-carbon bonds. A chlral diene ligand also asymmetrically creates quaternary spirocarbon stereocenters with high enantiomeric purity.
