146616-42-4

Basic information

• Product Name: tetrachloro{bis(2-phenoxoethyl) succinate-O,O'}titanium(IV)
• CAS NO: 146616-42-4
• Molecular Weight: 548.083
• Mol File: 146616-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetrachloro{bis(2-phenoxoethyl) succinate-O,O'}titanium(IV)(CAS DataBase Reference)
• NIST Chemistry Reference: tetrachloro{bis(2-phenoxoethyl) succinate-O,O'}titanium(IV)(146616-42-4)
• EPA Substance Registry System: tetrachloro{bis(2-phenoxoethyl) succinate-O,O'}titanium(IV)(146616-42-4)

Safety Data

• Hazardous Substances Data: 146616-42-4(Hazardous Substances Data)

Upstream product

• 7460-86-8 bis-(2-phenoxyethyl) succinate 
• 7550-45-0 titanium tetrachloride 

Relevant articles and documents

Reactions of TiCl4 with diesters. Crystal structures of and

Direct reactions of TiCl4 with diethyl malonate in n-hexane or with bis(2-phenoxoethyl) succinate in toluene yield the crystalline compounds (1) and (2), respectively.The crystal structures of both complexes have been determined by a single crystal X-ray diffraction study, and refined by full-matrix least-squares techniques to an R of 0.034 and 0.038 for 1575 and 1490 independent non-zero reflections for 1 and 2, respectively.Crystals of 1 are monoclinic, space group P21/c, Z=4, a=7.716(10), b=18.21(2), c=12.384(10) Angstroem, β=127.29(8) deg.Crystals of 2 are triclinic, space group P, Z=2, a=8.680(12), b=10.178(11), c=14.398(15) Angstroem, α=78.45(9), β=74.16(9), γ=88.45(9) deg.The titanium atoms in 1 and 2 are octahedrally-coordinated by four chlorine atoms and two carbonyl oxygen atoms of coordinated diester molecules.The titanium atoms and the chelate ligand atoms form the six-membered ring in 1 and the seven-membered ring in 2.