14664-88-1

Basic information

• Product Name: 2-Deuterio-2-phenyl-1,3-dithian
• Synonyms: 2-Deuterio-2-phenyl-1,3-dithian
• CAS NO: 14664-88-1
• Molecular Weight: 197.329
• Mol File: 14664-88-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Deuterio-2-phenyl-1,3-dithian(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Deuterio-2-phenyl-1,3-dithian(14664-88-1)
• EPA Substance Registry System: 2-Deuterio-2-phenyl-1,3-dithian(14664-88-1)

Safety Data

• Hazardous Substances Data: 14664-88-1(Hazardous Substances Data)

Upstream product

• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 86201-64-1 2-phenyl-1,3-dithian-2-ylium tetrafluoroborate 
• 100-52-7 benzaldehyde 
• 109-80-8 1.3-propanedithiol 
• 3592-47-0 Benzaldehyde-d 

Downstream Products

• 4181-90-2 (R)-(α-2H)benzyl alcohol 
• 3481-15-0 (S)-[α-D]-benzyl alcohol 
• 3592-47-0 Benzaldehyde-d 

Relevant articles and documents

Tandem Addition/Electrocyclization/Benzylation of Alkyl Aryl-1,3-dienes and Aromatic Aldehydes: Access to Highly Substituted Indenes

BF3·Et2O-mediated synthesis of multisubstituted indenes from alkyl aryl-1,3-dienes and aromatic aldehydes through tandem addition/4π-electrocyclization/benzylation via tetrahydroindeno-oxepine/quinone methide followed by an intramole

2-(3,5-Dinitrophenyl)-1,3-dithiane carbanion: A benzylic anion with a low energy triplet state

Calculations at the DFT level predict that benzyl anions with strong π-electron-withdrawing groups in the meta position(s) have low energy diradical or triplet electronic states. Specifically, the 2-(3,5-dinitrophenyl)- 1,3-dithiane carbanion is predicted

Enzyme-Catalyzed Organic Synthesis: NAD(P)H Cofactor Regeneration by Using Glucose 6-Phosphate and the Glucose-6-Phosphate Dehydrogenase from Leuconostoc mesenteroides

Glucose 6-phosphate dehydrogenase (from Leuconostoc mesenteroides) and glucose 6-phosphate comprise a useful system for regeneration of reduced nicotinamide cofactors for use in enzyme-catalyzed organic sysnthesis.This enzyme is approximately equally active in reduction of NAD and NADP.It is commercially available, inexpensive, stable, and easily immobilized.Glucose 6-phosphate can be prepared in quantity by hexokinase-catalysed phosphorylation of glucose by ATP (coupled with ATP regeneration) or by other methods.The operation in this regeneration system is illustrated by syntheses of enantiomerically enriched D-lactic acid (0.4 mol, enantiomeric excess 95percent) and (S)-benzyl-α-d1 alcohol (0.4 mol, enantiomeric excess 95percent) and by synthesis of treo-DS(+)-isocitric acid (0.17 mol).Factors influencing the stability of NAD(P)(H) in solution have been explored.