146792-91-8Relevant articles and documents
The photochemistry of various para-substituted tetrafluorophenyl azides in acidic media and the formation of nitrenium ions
Michalak, Jacek,Zhai, Hong Bin,Platz, Matthew S.
, p. 14028 - 14036 (1996)
Laser flash photolysis of polyfluorinated aryl azides in acetonitrile at ambient temperature produces singlet nitrenes which have lifetimes of tens to hundreds of nanoseconds. The lifetimes are controlled by ring expansion and intersystem crossing to the