1469468-10-7

Basic information

• Product Name: C₂₈H₃₃ClIrNO₂
• Synonyms: C₂₈H₃₃ClIrNO₂
• CAS NO: 1469468-10-7
• Molecular Weight: 643.249
• Mol File: 1469468-10-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₂₈H₃₃ClIrNO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₈H₃₃ClIrNO₂(1469468-10-7)
• EPA Substance Registry System: C₂₈H₃₃ClIrNO₂(1469468-10-7)

Safety Data

• Hazardous Substances Data: 1469468-10-7(Hazardous Substances Data)

Upstream product

• 12354-84-6 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 

Relevant articles and documents

Cyclometalated iridium complexes as highly active catalysts for the hydrogenation of imines

A robust cyclometalated iridium catalyst has been developed for highly effective hydrogenation of imines. With very low catalyst loading (down to 0.005%), good to excellent yields have been achieved for a range of substrates in a short reaction time under

CATALYST COMPOUNDS

The present invention relates to an iridium-based catalyst compound for hydrogenating reducible moieties, especially imines and iminiums, the catalyst compounds being defined by the formulas: where ring B is either itself polycyclic, or ring B together with R is polycyclic. The catalysts of the invention are particularly effective in reductive amination procedures 10 which involve the in situ generation of the imine or iminium under reductive hydrogenative conditions.