147165-86-4Relevant articles and documents
Switch in regioselectivity of epoxide ring-opening by changing the organometallic reagent
Galvez, Jose A.,Diaz De Villegas, Maria D.,Badorrey, Ramon,Lopez-Ram-De-Viu, Pilar
experimental part, p. 8155 - 8162 (2012/01/04)
The regio- and stereoselective ring-opening of a 2-(2′-oxiranyl)-1,2, 3,6-tetrahydropyridine using organometallic reagents is reported. The choice of the organometallic reagent determines the formation of either 2-[(R)-1-hydroxyalkyl]- or 2-[(S)-2-hydroxy
Iodocyclization of Homoallylic Hydroxylamines Derived from D-Glyceraldehyde
Dhavale, Dilip D.,Gentilucci, Luca,Piazza, Maria Giulia,Trombini, Claudio
, p. 1289 - 1296 (2007/10/02)
The reaction of allylmagnesium chloride with nitrone 1 derived from D-glyceraldehyde affords two diastereoisomeric homoallylic hydroxylamines 2a and 3a which, after separation and O-silylation, are subjected to iodocyclization using N-iodosuccinimide.The