1472-00-0

Basic information

• Product Name: cis-2,5-bis(hydroxymethyl)-tetrahydrofuran ditosylate
• Synonyms: cis-2,5-bis(hydroxymethyl)-tetrahydrofuran ditosylate
• CAS NO: 1472-00-0
• Molecular Weight: 440.538
• Mol File: 1472-00-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: cis-2,5-bis(hydroxymethyl)-tetrahydrofuran ditosylate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2,5-bis(hydroxymethyl)-tetrahydrofuran ditosylate(1472-00-0)
• EPA Substance Registry System: cis-2,5-bis(hydroxymethyl)-tetrahydrofuran ditosylate(1472-00-0)

Safety Data

• Hazardous Substances Data: 1472-00-0(Hazardous Substances Data)

Upstream product

• 2144-40-3 cis-2,5-bis(hydroxymethyl)tetrahydrofuran 
• 98-59-9 p-toluenesulfonyl chloride 
• 2240-81-5 cis-tetrahydrofuran-2,5-dicarboxylic acid 
• 67-47-0 5-hydroxymethyl-2-furfuraldehyde 
• 4282-32-0 furan-2,5-dicarboxylic acid dimethyl ester 
• 1472-01-1 cis-2,5-bis(methoxycarbonyl)tetrahydrofuran 

Downstream Products

• 99969-71-8 2-(8-oxa-3-aza-bicyclo[3.2.1]oct-3-yl)-ethanol 
• 280-13-7 8-oxa-3-aza-bicyclo[3.2.1]octane 
• 81340-23-0 cis-2,5-bis<<2-<(2-tetrahydropyranyl)oxy>phenoxy>methyl>tetrahydrofuran 
• 246543-70-4 3-exo-[4-(4-Fluorophenoxy)benzenesulfonylamino]-8-oxabicyclo[3.2.1]octane-3-carboxylic acid 
• 815576-04-6 (1R,3S,5S)-3-[4-(4-Fluoro-phenoxy)-benzenesulfonylamino]-8-oxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester 
• 856176-37-9 8-oxabicyclo[3.2.1]octane-3-carboxylic acid 
• 54745-75-4 3-benzyl-8-oxa-3-aza-bicyclo[3.2.1]octane 
• 1448423-30-0 2,5-dioxohexane-1,6-diyl bis(4-methylbenzenesulfonate) 

Relevant articles and documents

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SYNTHESIS OF DIACIDS, DIALDEHYDES, OR DIAMINES FROM THF-DIOLS

A simple and elegant chemical process for the synthesis of oxygenated products, such as acids and aldehydes, or other derivative products, such as amines and nitriles, of cyclic bifunctional molecules made from renewable, bio-based sources such as HMF and

Catalytic hydrogenation of 5-hydroxymethylfurfural in aqueous medium

The catalytic hydrogenation of 5-hydroxymethylfurfural (HMF) in aqueous medium was studied in presence of Ni, Cu, Pt, Pd, Ru based catalysts.In neutral aqueous mdeium, two major products are abtained in very good yields: 2,5-bis-hydroxymethylfuran (Cu, Pt, Ru) and 2,5-bis-hydroxymethyltetrahydrofuran-cis (Ni, Pd, Ru).In acidic aqueous medium, hydrogenolysis reactions occur and the hydrogenation of HMF leads to two other products: 1-hydroxyhexane-2,5-dione and hexane-1,2,5-triol, mainly in presence of Pt and Ru.A mechanism of formation of these two compounds is proposed.Key words: 5-hydroxymethylfurfural / hydrogenation / hydrogenolysis