147298-36-0

Basic information

• Product Name: 1-(((2-bromoallyl)oxy)methyl)-4-methoxybenzene
• Synonyms: 1-(((2-bromoallyl)oxy)methyl)-4-methoxybenzene
• CAS NO: 147298-36-0
• Molecular Weight: 257.127
• Mol File: 147298-36-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(((2-bromoallyl)oxy)methyl)-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(((2-bromoallyl)oxy)methyl)-4-methoxybenzene(147298-36-0)
• EPA Substance Registry System: 1-(((2-bromoallyl)oxy)methyl)-4-methoxybenzene(147298-36-0)

Safety Data

• Hazardous Substances Data: 147298-36-0(Hazardous Substances Data)

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 513-31-5 2-bromoallyl bromide 
• 14289-62-4 1-(allyloxymethyl)-4-methoxybenzene 
• 1262961-64-7 C₁₁H₁₄Br₂O₂ 
• 598-19-6 2-bromoallyl alcohol 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 1236063-71-0 1-methoxy-4-[(2-methylenenon-3-ynyloxy)methyl]benzene 
• 4039-83-2 3-(4-methoxybenzyloxy)propyne 
• 147298-38-2 [(1S,2R)-2-Hydroxy-1-isobutyl-3-(4-methoxy-benzyloxymethyl)-but-3-enyl]-carbamic acid benzyl ester 
• 771531-69-2 (E)-4-(4-Methoxy-benzyloxymethyl)-penta-2,4-dien-1-ol 
• 147298-43-9 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S)-2-benzyloxycarbonylamino-1-[1-(4-methoxy-benzyloxymethyl)-vinyl]-4-methyl-pentyl ester 

Relevant articles and documents

Catalytic Enantioselective Synthesis of Halocyclopropanes

A catalytic asymmetric synthesis of halocyclopropanes is described. The developed method is based on a carbenoid cyclopropanation of 2-haloalkenes with tert-butyl α-cyano-α-diazoacetate using a chiral rhodium catalyst that permits access to a broad range

TBAF-promoted elimination of vicinal dibromides having an adjacent O-functional group: Syntheses of 2-bromoalk-1-enes and alkynes

Syntheses of 2-bromoalk-1-enes and alkynes were achieved in good yields by dehydrobromination of vicinal dibromides with tetrabutylammonium fluoride. Neighboring O-functional-group participation is important in determining elimination reactivity. Georg Thieme Verlag Stuttgart New York.

TBAF-promoted dehydrobrominations of vicinal dibromides having an adjacent O-functional group

Regioselective HBr elimination of vicinal dibromides having an adjacent oxygen functional group to give the corresponding 2-bromoalk-1-enes was controlled using 1.1 equivalents of TBAF. Two-step elimination to give the corresponding alkynes was controlled using 5.0 equivalents of TBAF. High yield and high selectivity require the presence of an oxygen functional group at the neighboring position of the elimination site.