147406-87-9

Basic information

• Product Name: (2R,6R,8S,12S)-1-aza-10-oxo-12-phenyl-4-thiatricyclo<6.4.0^1,8.0^2,6>dodecan-9-one
• Synonyms: (2R,6R,8S,12S)-1-aza-10-oxo-12-phenyl-4-thiatricyclo<6.4.0^1,8.0^2,6>dodecan-9-one
• CAS NO: 147406-87-9
• Molecular Weight: 275.371
• Mol File: 147406-87-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,6R,8S,12S)-1-aza-10-oxo-12-phenyl-4-thiatricyclo<6.4.0^1,8.0^2,6>dodecan-9-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,6R,8S,12S)-1-aza-10-oxo-12-phenyl-4-thiatricyclo<6.4.0^1,8.0^2,6>dodecan-9-one(147406-87-9)
• EPA Substance Registry System: (2R,6R,8S,12S)-1-aza-10-oxo-12-phenyl-4-thiatricyclo<6.4.0^1,8.0^2,6>dodecan-9-one(147406-87-9)

Safety Data

• Hazardous Substances Data: 147406-87-9(Hazardous Substances Data)

Upstream product

• 72867-23-3 methyl 2-(allylthio)acetate 
• 58965-04-1 allyl 2-hydroxyethyl sulfide 
• 120983-16-6 2‐(prop‐2‐en‐1‐ylsulfanyl)-acetaldehyde 
• 144896-92-4 (5S)-5-phenylmorpholin-2-one 

Downstream Products

• 147406-88-0 (2S,6S,8R,9R)-1-aza-8,9-dimethyl-4-oxa-2-phenylbicyclo<4.3.0^1,6>nonan-5-one 
• 147512-07-0 (2S,4R,5R)-4,5-dimethylproline ethyl ester 

Relevant articles and documents

Enantiocontrolled construction of bicyclic proline derivatives via one-pot generation and intramolecular trapping of chiral stabilised azomethine ylids

Aldehydes possessing unsaturation at C-5 or C-6 condense with nylmorpholin-2-one (1), generating chiral stabilised azomethine ylids which undergo concommitant diastereospecific intramolecular 3+2 dipolar cycloaddition to furnish adducts (2), (4), and (5)