147727-23-9

Basic information

• Product Name: C₁₅H₁₄N₂O₂
• Synonyms: C₁₅H₁₄N₂O₂
• CAS NO: 147727-23-9
• Molecular Weight: 254.288
• Mol File: 147727-23-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₄N₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₄N₂O₂(147727-23-9)
• EPA Substance Registry System: C₁₅H₁₄N₂O₂(147727-23-9)

Safety Data

• Hazardous Substances Data: 147727-23-9(Hazardous Substances Data)

Upstream product

• 1027185-39-2 (4R,5S)-5-(3-Cyano-indol-1-ylmethyl)-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid 2-thioxo-2H-pyridin-1-yl ester 

Downstream Products

• 5685-06-3 4-methylthiazole-2(3H)-thione 

Relevant articles and documents

Intramolecular Addition of a Dioxolanyl Radical to the Indole Nucleus: Preparation of Enantiomerically Pure, Oxygenated Perhydro-3H-pyrroloindoles

The cyclization of dioxolanyl radicals, which were generated by the Barton tartrate-derived thiohydroxamate ester (mixed anhydride) procedure, with an indole nucleus has been explored.The products derived from these reactions have been identified and their chemistry investigated with the goal of uncovering new entries into enantiomerically pure, mitomycin-like structures.Thus, the photolysis of 1-hydroxy-2-thiopyridone ester 8c and 1-hydroxy-4-methylthiazole-2(3H)-thione ester 8d has been conducted with UV and visible light.The photochemistry of the products, namely, dimer 9, dihydroindole 12a, indole 11, and thiazole 13c, derived from the thiohydroxamate esters and putative intermediates 18a and 18b, was also explored.