14799-60-1

Basic information

• Product Name: 1-phenyl-2-cyclopropylethylene
• Synonyms: 1-phenyl-2-cyclopropylethylene
• CAS NO: 14799-60-1
• Molecular Weight: 144.216
• Mol File: 14799-60-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-phenyl-2-cyclopropylethylene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-2-cyclopropylethylene(14799-60-1)
• EPA Substance Registry System: 1-phenyl-2-cyclopropylethylene(14799-60-1)

Safety Data

• Hazardous Substances Data: 14799-60-1(Hazardous Substances Data)

Upstream product

• 1449-46-3 benzyltriphenylphosphonium bromide 
• 1489-69-6 Cyclopropanecarboxaldehyde 
• 1515-78-2 buta-1,3-dien-1-ylbenzene 
• 74-95-3 1,1-dibromomethane 
• 103-64-0 bromostyrene 
• 3002-94-6 cyclopropyllithium 
• 78814-45-6 [(E)-2-(1-Methylselanyl-cyclopropyl)-vinyl]-benzene 
• 14799-82-7 (cyclopropylmethyl)triphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 6226-35-3 (2-Cyclopropyl-2-phenyl-ethyl)-tosylat 

Downstream Products

• 426265-79-4 C₆H₅(CH₃)2SiCH(C₆H₅)CHCHCH₂CH₂BO₂C₂(CH₃)4 
• 37689-22-8 3-phenylcyclopentene 
• 3909-96-4 (1E,3E)-1-phenyl-1,3-pentadiene 
• 3481-02-5 cyclopropyl phenyl ketone 
• 34650-69-6 1-cyclopropyl-2-phenylethane-1,2-dione 
• 1261084-15-4 ((CH₃)3C)3PCH(C₆H₅)CHCHCH₂CH₂B(C₆F₅)3 
• 1261084-11-0 ((CH₃)3C)3PCH(CHCHC₆H₅)CH₂CH₂B(C₆F₅)3 

Relevant articles and documents

Visible photocatalysis of novel oxime phosphonates: Synthesis of β-aminophosphonates

A novel type of oxime phosphonate was synthesized and used in the intermolecular cascade radical addition reaction of alkenes to access β-aminophosphonates via visible-light-driven N-centered iminyl radical-mediated and redox-neutral selective C-P single-bond cleavage in an active phosphorus radical route. The procedure is characterized by its ability to achieve the construction of Csp3-P and Csp3-N bonds without the requirement for oxidants and bases.

Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents

Palladium-catalysed cross-coupling of secondary C(sp3) organometallic reagents has been a long-standing challenge in organic synthesis, due to the problems associated with undesired isomerisation or the formation of reduction products. Based on our recently developed catalytic C-C bond formation with organolithium reagents, herein we present a Pd-catalysed cross-coupling of secondary alkyllithium reagents with aryl and alkenyl bromides. The reaction proceeds at room temperature and on short timescales with high selectivity and yields. This methodology is also applicable to hindered aryl bromides, which are a major challenge in the field of metal catalysed cross-coupling reactions.