148089-61-6Relevant articles and documents
REACTIONS OF SODIUM ETHENECHALCOGENOLATES WITH HEXAFLUOROBENZENE
Amosova, S. V.,Gostevskaya, V. I.,Gavrilova, G. M.,Afonin, A. V.,Romanenko, L. S.,Stefanik, L.
, p. 1154 - 1157 (2007/10/02)
The nucleophilic susbtitution of the fluorine atoms in hexafluorobenzene in reaction with sodium ethenethiolate and etheneselenolate, produced by the cleavage of divinyl sulfide and divinyl selenide with sodium in liquid ammonia, takes place at 20-30 deg C in DMFA with the formation of 1,2,4,5-tetrafluoro-3,6-bisbenzenes and 1,4-difluoro-2,3,5,6-tetrakis(vinylthio)benzene.The formation of the vinylthio-substituted fluorobenzenes and their yields probably depend on the basicity of the medium, the reagent ratio, and the order of mixing.