1483-68-7Relevant articles and documents
Desulphurisation-Dimerisation of Dithioacetals with W(CO)6
Yeung, Lam Lung,Yip, Yu Chi,Luh, Tien-Yau
, p. 981 - 983 (1987)
Dithioacetals undergo desulphurisation-dimerisation to give the corresponding dimeric alkenes in good to excellent yields on treatment with W(CO)6.
Mechanosynthesis of Odd-Numbered Tetraaryl[n]cumulenes
Ardila-Fierro, Karen J.,Bolm, Carsten,Hernández, José G.
, p. 12945 - 12949 (2019/08/01)
A mechanochemical synthesis of one-dimensional carbon allotrope carbyne model compounds, namely tetraaryl[n]cumulenes (n=3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation-type reaction and the implementation of a solvent-free, acid-free reductive elimination with tin(II) chloride by ball milling.
Synthesis of cyano-substituted diaryltetracenes from tetraaryl[3]cumulenes
Gawel, Przemyslaw,Dengiz, Cagatay,Finke, Aaron D.,Trapp, Nils,Boudon, Corinne,Gisselbrecht, Jean-Paul,Diederich, Francois
, p. 4341 - 4345 (2014/05/06)
A versatile, two-step synthesis of highly substituted, cyano-functionalized diaryltetracenes has been developed, starting from easily accessible tetraaryl[3]cumulenes. This unprecedented transformation is initiated by [2+2] cycloaddition of tetracyanoethy
Palladium-catalyzed arylation of butadiynes
Dyker,Borowski,Henkel,Kellner,Dix,Jones
, p. 8259 - 8262 (2007/10/03)
Diarylbutadiynes 1 undergo a palladium-catalyzed coupling reaction with aryl halides 2 to give tetraarylbutatrienes 3, which may further react to benzofulvenes 6 depending on the reaction temperature and the type of aryl groups. (C) 2000 Elsevier Science