14845-78-4

Basic information

• Product Name: Methylene, (4-chlorophenyl)phenyl-
• CAS NO: 14845-78-4
• Molecular Formula: C13H9Cl
• Molecular Weight: 200.667
• Mol File: 14845-78-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methylene, (4-chlorophenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methylene, (4-chlorophenyl)phenyl-(14845-78-4)
• EPA Substance Registry System: Methylene, (4-chlorophenyl)phenyl-(14845-78-4)

Safety Data

• Hazardous Substances Data: 14845-78-4(Hazardous Substances Data)

Upstream product

• 1140-33-6 1-chloro-4-(diazo(phenyl)methyl)benzene 

Downstream Products

• 7364-23-0 1-chloro-4-(methoxy(phenyl)methyl)benzene 

Relevant articles and documents

The Absolute Kinetics of Several Reactions of Substituted Diphenylcarbenes

4,4'-dibromo-, 4-bromo-, 4,4'-dichloro-, 4-chloro-, 4-methyl-, 4,4'-dimethyl-, 4-phenyl-, 4-carbomethoxyl-, 4-cyano-, 4-cyano-4'-methyl-, and 4,4'-dimethyldiphenyldiazomethane were studied by laser flash photolysis.Excitation of the diazo compounds at 308 nm produced the corresponding diarylcarbenes.The kinetics of the reaction of the substituted carbenes with alkanes and methanol were examined.Hydrogen abstraction rates are largely insensitive to ring substitution, while the methanol reaction is accelerated considerably by p-methyl substitution and retarded by a para electron-withdrawing substituent.