148573-90-4

Basic information

• Product Name: PdCl₂(((C₆H₅)2PC₆H₄Si(CH₃)2OSi(CH₃)2OSi(CH₃)2C₆H₄P(C₆H₅)2))
• CAS NO: 148573-90-4
• Molecular Weight: 906.356
• Mol File: 148573-90-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PdCl₂(((C₆H₅)2PC₆H₄Si(CH₃)2OSi(CH₃)2OSi(CH₃)2C₆H₄P(C₆H₅)2))(CAS DataBase Reference)
• NIST Chemistry Reference: PdCl₂(((C₆H₅)2PC₆H₄Si(CH₃)2OSi(CH₃)2OSi(CH₃)2C₆H₄P(C₆H₅)2))(148573-90-4)
• EPA Substance Registry System: PdCl₂(((C₆H₅)2PC₆H₄Si(CH₃)2OSi(CH₃)2OSi(CH₃)2C₆H₄P(C₆H₅)2))(148573-90-4)

Safety Data

• Hazardous Substances Data: 148573-90-4(Hazardous Substances Data)

Upstream product

• 15617-18-2 bis(benzonitrile)palladium(II) dichloride 
• 107394-34-3 hexamethyl-1,5-bistrisiloxane 

Relevant articles and documents

Novel phosphine-palladium complex-catalysed regioselective allylation of a Grignard reagent

The novel phosphine compounds hexamethyl-1,5-bis[p- (diphenyphosphino)phenyl] trisiloxane (1) and 2,4,6,8-tetrakis [p-(diphenylphosphino)phenyl]-2,4,6,8- tetramethylcyclotetrasiloxane (2) containing two or more triphenylphosphine units were effective as ligands in catalysts for Grignard cross-coupling. Especially the palladium complex of cyclotetrasiloxane ligand 2 effectively catalysed the regioselective cross-coupling of allylic ethers with phenylmagnesium bromide to afford the non-terminal alkene.