1489-23-2

Basic information

• Product Name: N-(2-(phenylthio)phenyl)acetamide
• Synonyms: N-(2-(phenylthio)phenyl)acetamide
• CAS NO: 1489-23-2
• Molecular Weight: 243.329
• Mol File: 1489-23-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: N-(2-(phenylthio)phenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(phenylthio)phenyl)acetamide(1489-23-2)
• EPA Substance Registry System: N-(2-(phenylthio)phenyl)acetamide(1489-23-2)

Safety Data

• Hazardous Substances Data: 1489-23-2(Hazardous Substances Data)

Upstream product

• 533-17-5 N-(2-chlorophenyl)acetamide 
• 3111-52-2 potassium thiophenolate 
• 1134-94-7 2-phenylsulfanyl-aniline 
• 75-36-5 acetyl chloride 
• 103-84-4 Acetanilid 
• 882-33-7 diphenyldisulfane 
• 127-19-5 N,N-dimethyl acetamide 
• 136-95-8 2-amino-benzthiazole 
• 1201683-08-0 N-(2-(phenylthio)phenyl)cyanamide 
• 64-19-7 acetic acid 
• 591-50-4 iodobenzene 
• 930-69-8 sodium thiophenolate 
• 4171-83-9 2-nitrophenyl phenyl sulfide 
• 577-19-5 2-nitrophenyl bromide 

Downstream Products

• 16714-31-1 phenyl-2-amine-phenylsulfoxide 
• 4273-98-7 2-aminophenyl phenyl sulfone 
• 16714-29-7 acetic acid-(2-benzenesulfonyl-anilide) 
• 16714-30-0 acetic acid-(2-benzenesulfinyl-anilide) 
• 1134-94-7 2-phenylsulfanyl-aniline 

Relevant articles and documents

Manganese(I) Catalyzed α-Alkenylation of Amides Using Alcohols with Liberation of Hydrogen and Water

Herein, unprecedented manganese-catalyzed direct α-alkenylation of amides using alcohols is reported. Aryl amides are reacted with diverse primary alcohols, which provided the α,β-unsaturated amides in moderate to good yields with excellent selectivity. Mechanistic studies indicate that Mn(I) catalyst oxidizes the alcohols to their corresponding aldehydes and also plays an important role in efficient C═C bond formation through aldol condensation. This selective olefination is facilitated by metal-ligand cooperation by the aromatization-dearomatization process operating in the catalytic system. Biorenewable alcohols are used as alkenylation reagents for the challenging α-alkenylation of amides with the highly abundant base metal manganese as a catalyst, which results in water and dihydrogen as the only byproduct, making this catalytic transformation attractive, sustainable, and environmentally benign.

Copper-(II) Catalyzed N-Formylation and N-Acylation of Aromatic, Aliphatic, and Heterocyclic Amines and a Preventive Study in the C-N Cross Coupling of Amines with Aryl Halides

A Cu-(II) catalyzed N-formylation and N-acylation of amines with moderate to excellent yields, using N, N-dimethyl formamide (DMF) and N, N-dimethyl acetamide (DMA) as a formyl and acylating sources in the presence of 1,2,4-triazole is reported. This novel, highly efficient and simple protocol shows broad substrate scope for aliphatic, aromatic, and heterocyclic amines. In addition, the conditions to prevent N-formylation and N-acylation impurities in the C?N cross coupling of amines and aryl halides are described typically when DMF and DMA are used as solvents, with various catalysts, ligands, and bases.

NOVEL TRIAZINE COMPOUND, AND ORGANIC ELECTRONIC ELEMENT AND PLANT-GROWING LIGHTING THAT USE THE SAME

PROBLEM TO BE SOLVED: To provide a triazine compound which has a high triplet energy level and excellent heat resistance, and can be used as an organic electronic element material realizing an element with high efficiency, low voltage and a long life. SOLUTION: In the triazine compound, as represented by the general formula [1] in the figure, a triazine backbone moiety is linked to a dibenzofuran or dibenzothiophene backbone moiety via a biphenyl backbone moiety, where X is an oxygen atom or sulfur atom. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPO&INPIT