148932-09-6Relevant articles and documents
Novel Cycloaddition Reactions of Methacryloyl Isocyanate with Enamines
Tsuge, Otohiko,Hatta, Taizo,Mizuguchi, Ryuzo,Kato, Hisayoshi
, p. 631 - 634 (2007/10/02)
Methacryloyl isocyanate (MAI) functioned as an ambident heterodiene in the cycloaddition reactions. Thus, enamines added not only to the acyl isocyanato moiety, but also to the enone moiety in MAI. Regiochemistry of this cycloaddition markedly depended on the reaction conditions. The pathways for the formation of products are also described.