14904-40-6

Basic information

• Product Name: Benzenepropanenitrile, b-[(trimethylsilyl)oxy]-
• CAS NO: 14904-40-6
• Molecular Formula: C12H17NOSi
• Molecular Weight: 219.359
• Mol File: 14904-40-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenepropanenitrile, b-[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanenitrile, b-[(trimethylsilyl)oxy]-(14904-40-6)
• EPA Substance Registry System: Benzenepropanenitrile, b-[(trimethylsilyl)oxy]-(14904-40-6)

Safety Data

• Hazardous Substances Data: 14904-40-6(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 7677-24-9 trimethylsilyl cyanide 
• 614-16-4 Benzoylacetonitrile 
• 75-77-4 chloro-trimethyl-silane 
• 96-09-3 styrene oxide 
• 86208-59-5 3-trimethylsily;-4,5-dihydro-5-phenylisoxazole 
• 100-52-7 benzaldehyde 
• 590-17-0 cyanomethyl bromide 
• 18293-53-3 2-trimethylsilylacetonitrile 
• 14904-37-1 Sodium acetonitrile 

Downstream Products

• 4360-47-8 cinnamonitrile 
• 73627-97-1 3-hydroxy-3-phenylpropanenitrile 

Relevant articles and documents

Efficient ring opening of epoxides with trimethylsilyl azide and cyanide catalyzed by erbium(III) triflate

Epoxides can be opened under neutral conditions with TMSN3 and TMSCN in the presence of catalytic amounts of Lewis acid, affording the corresponding ring-opened compounds in high yields.

Ring opening of oxiranes catalyzed by Mn-Salen immobilized mesoporous materials

Mn-Salen Immobilized mesoporous materials were found to be efficient solid catalysts for the nucleophilic ring opening of oxiranes with TMSN3, TMSCN and aniline.

Improved Synthesis of β-Trimethylsilyloxy Nitriles in a Solvent-free Reaction under Classical Heating or Microwave Activation

Trimethylsilylacetonitrile (2) reacts with several aldehydes 1 to afford β-trimethylsilyloxy nitriles 3 without solvent either under microwave irradiation or in an oil-bath, in the presence of adjusted catalytic amounts of piperidine; yields are equivalen