149399-58-6Relevant articles and documents
Iron-Catalyzed Oxidation of 4-Substituted N,N-Dimethylanilines with Molecular Oxygen in the Presence of Benzoyl Cyanide
Murata, Satoru,Teramoto, Koji,Miura, Masahiro,Nomura, Masakatsu
, p. 1297 - 1298 (1993)
The oxidation of 4-substituted N,N-dimethylanilines with molecular oxygen using a catalytic amount of iron(III) chloride efficiently proceeded in the presence of benzoyl cyanide to give the corresponding N-cyanomethyl-N-methylanilines along with N-methylformanilides.
Copper-catalyzed synthesis of α-amino nitriles through methyl transfer from DMF to aromatic amines
Yuan, Zaifeng,Li, Na,Zhu, Chunyu,Xia, Chengfeng
supporting information, p. 2854 - 2857 (2018/03/23)
A copper-catalyzed activation of C(sp3)-H bonds of DMF at room temperature was developed, which results in methyl transfer to aromatic amines for efficient synthesis of exceedingly valuable α-amino nitriles. This process features excellent functional group tolerance, a broad substrate scope, and high activity under ambient conditions.
Seven-coordinated chiral uranyl(VI) salen complex as effective catalyst for C–H bond activation of dialkylanilines under visible light
Azam, Mohammad,Al-Resayes, Saud I.,Trzesowska-Kruszynska, Agata,Kruszynski, Rafal,Kumar, Pawan,Jain, Suman L.
, p. 177 - 183 (2017/01/28)
A new chiral uranyl(VI) complex incorporating a tetradentate salen ligand is reported. The synthesized uranyl complex is studied by microanalyses, spectroscopic and X-ray diffraction studies. The structural studies reveal a slightly distorted pentagonal bipyramid coordination environment around uranyl ion. Interestingly, the uranyl complex was found to be potential visible light active catalyst for C–H bond functionalization of dialkylanilines, and afforded moderate to excellent yield of corresponding α-aminonitriles when exposed to visible light for 8?h in the presence of NaCN and acetic acid as cyanide source, and H2O2as oxidant.
Potassium thiocyanate as source of cyanide for the oxidative α-cyanation of tertiary amines
Wagner, Alexander,Ofial, Armin R.
, p. 2848 - 2854 (2015/03/18)
Oxidation at the sulfur of the safe-to-handle potassium thiocyanate releases cyanide units that are trapped in the presence of co-oxidized tertiary amines to form α-amino nitriles. These cyanations work in aqueous solutions and do not require a catalyst,