149427-85-0Relevant articles and documents
Deplacements homolytiques intramoleculaires. 4. Thermolyse du perpentene-4 oate de tert-butyle dans les acides et leurs derives: preparation de γ-butyrolactones substituees en 4 par un groupe comportant une fonction ester, acide ou nitrile
Kharrat, A.,Gardrat, C.,Maillard, B.
, p. 2522 - 2528 (2007/10/02)
The thermolysis of tert-butylperpent-4-enoate in various solvents ZH (carboxylic acids, anhydrides, methyl esters, nitriles) led to γ-butyrolactones 4-substituted by the group ZCH2 with good yields.The acidic treatment of the lactones 4 and 6 derived from non-functionalized alkanoic acids and methyl esters gave respectively the isomerized lactones 5 and 7, increasing the synthetic interest of the studied homolytic reaction.