149467-73-2

Basic information

• Product Name: methyl 4-phenyl-5-methylnicotinate
• Synonyms: methyl 4-phenyl-5-methylnicotinate
• CAS NO: 149467-73-2
• Molecular Weight: 227.263
• Mol File: 149467-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4-phenyl-5-methylnicotinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-phenyl-5-methylnicotinate(149467-73-2)
• EPA Substance Registry System: methyl 4-phenyl-5-methylnicotinate(149467-73-2)

Safety Data

• Hazardous Substances Data: 149467-73-2(Hazardous Substances Data)

Upstream product

• 103669-71-2 (Z)-methyl 2-(bromomethyl)-3-phenylacrylate 
• 18020-59-2 methyl 3-hydroxy-2-methylidene-3-phenylpropionate 
• 100-52-7 benzaldehyde 
• 591-50-4 iodobenzene 
• 29681-45-6 5-methylnicotinic acid methyl ester 

Relevant articles and documents

Palladium-catalyzed domino cyclization (5-exo/3-exo), ring- expansion by palladium rearrangement, and aromatization: An expedient synthesis of 4-arylnicotinates from Morita-Baylis-Hillman adducts

Various 4-arylnicotinate derivatives were synthesized via a palladium-catalyzed cascade reaction of N-(2-bromoallyl)-N-cinnamyltosylamides in a one-pot procedure in good yields. The reaction involves a domino 5-exo/3-exo carbopalladation, ring-expansion b