149856-87-1

Basic information

• Product Name: {(C₆H₅)2PCH₂P(C₆H₅)2Co₂(CCH₂S(CH₂)2SCH₂C)(CO)4}
• CAS NO: 149856-87-1
• Molecular Weight: 758.687
• Mol File: 149856-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(C₆H₅)2PCH₂P(C₆H₅)2Co₂(CCH₂S(CH₂)2SCH₂C)(CO)4}(CAS DataBase Reference)
• NIST Chemistry Reference: {(C₆H₅)2PCH₂P(C₆H₅)2Co₂(CCH₂S(CH₂)2SCH₂C)(CO)4}(149856-87-1)
• EPA Substance Registry System: {(C₆H₅)2PCH₂P(C₆H₅)2Co₂(CCH₂S(CH₂)2SCH₂C)(CO)4}(149856-87-1)

Safety Data

• Hazardous Substances Data: 149856-87-1(Hazardous Substances Data)

Upstream product

• 149856-57-5 {Co₂(CCH₂S(CH₂)2SCH₂C)(CO)6} 
• 2071-20-7 bis-diphenylphosphinomethane 
• 55975-76-3 2-butyne-1,4-diol-hexacarbonyldicobalt 

Relevant articles and documents

Synthesis of Hexacarbonyldicobalt-complexed Thiacycloalkynes

Reaction of 1R2CCR1R2OH)(CO)6> (R1 = R2 = H or Me; R1 = H, R2 = Me) with HS(CH2)nSH (n = 2-5) or HS(CH2)2OH in the presence of HBF4*OEt2 affords predominantely monomeric hexacarbonyldicobalt-complexed thiacycloalkynes.In many cases, especially with the longer chain dithiols, dimeric compounds are also formed as minor products and in some cases higher oligomers have also been characterised.Reaction of CCH2OH)(CO)6> with HSCH2CH(OH)CH2SH affords complexed thiacycloalkynes with pendant hydroxyl functionalities.The monomeric complexes undergo carbonyl substitution with bis(diphenylphosphino)me thane (dppm) and the X-ray crystal structure of has been determined.The molecule contains a co-ordinated 1,4-dithiacyclooct-6-yne which adopts two conformations in the solid state.The IR, mass, (1)H and (13)C NMR spectra of the new compounds are discussed.