150079-27-9

Basic information

• Product Name: Benzoic acid, 2-bromo-6-(trimethylsilyl)-
• CAS NO: 150079-27-9
• Molecular Formula: C10H13BrO2Si
• Molecular Weight: 273.202
• Mol File: 150079-27-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-bromo-6-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-bromo-6-(trimethylsilyl)-(150079-27-9)
• EPA Substance Registry System: Benzoic acid, 2-bromo-6-(trimethylsilyl)-(150079-27-9)

Safety Data

• Hazardous Substances Data: 150079-27-9(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 88-65-3 2-bromobenzoic-acid 
• 108-18-9 diisopropylamine 

Downstream Products

• 601-84-3 2,6-dibromobenzoic acid 

Relevant articles and documents

Selectivities in reactions of organolithium reagents with unprotected 2-halobenzoic acids

(Matrix presented) Exposing 2-fluorobenzoic acid (1a) to 2.2 equiv of LTMP at ca. -78°C leads to deprotonation at the 3-position whereas 2-chloro/bromobenzoic acids (1b,c) are lithiated adjacent to the carboxylate. The resulting dianions 3Li-1a and 6Li-1b