150112-08-6

Basic information

• Product Name: 25,26,27-trihydroxy-28-propoxycalix<4>arene
• Synonyms: 25,26,27-trihydroxy-28-propoxycalix<4>arene
• CAS NO: 150112-08-6
• Molecular Weight: 466.577
• Mol File: 150112-08-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 25,26,27-trihydroxy-28-propoxycalix<4>arene(CAS DataBase Reference)
• NIST Chemistry Reference: 25,26,27-trihydroxy-28-propoxycalix<4>arene(150112-08-6)
• EPA Substance Registry System: 25,26,27-trihydroxy-28-propoxycalix<4>arene(150112-08-6)

Safety Data

• Hazardous Substances Data: 150112-08-6(Hazardous Substances Data)

Upstream product

• 248590-47-8 25,26,27,28-tetrakis(hydroxy)calix[4]arene 
• 107-08-4 1-iodo-propane 
• 106-94-5 propyl bromide 

Downstream Products

• 143406-35-3 25,27-dihydroxy-26,28-dipropoxycalix[4]arene 
• 392743-43-0 25,26-dihydroxy-27,28-dipropoxycalix[4]arene 
• 1311286-74-4 25-benzoyloxy-27-propoxy-26,28-dihydroxycalix[4]arene 
• 1311286-78-8 25,26-dibenzoyloxy-27-propoxy-28-hydroxycalix[4]arene 
• 1187816-98-3 C₄₁H₄₁NO₅ 
• 150112-10-0 25-hydroxy-26,27-dipropoxy-28-(benzyloxy)calix<4>arene 
• 392334-67-7 25,27-bis(dimethylaminocarbonylmethoxy)-26-phenylmethoxy-28-propoxycalix[4]arene 
• 150112-09-7 25,27-dihydroxy-26-propoxy-28-(benzyloxy)calix<4>arene 

Relevant articles and documents

Regioselective upper-rim functionalizations of calix[4]arene by diphenylphosphino groups

The regioselective upper-rim functionalization of calix[4]arene have been performed to prepare all the multisubstituted diphenylphosphine derivatives. In addition, the X-ray structures of 5,17-dibromo-11,23-bis(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix [4]arene and 5,11,17,23-tetrakis(diphenylphosphino)-25,26,27,28-tetra-i-propoxy-calix[4] arene have been determined. Regioselective functionalizations have been achieved using methods that involve appropriate choices of bases, alkyllithium-solvent systems, stoichiometry, and reaction times. A new and convenient method for selectively preparing derivitized calix[4]arenes at proximal positions in relative large scale quantity has been developed and involves a transesterification of the distal diester derivative into the proximal isomer.