150331-74-1

Basic information

• Product Name: chloro(bromo)(2,4,6-triisopropylphenyl)phosphane
• Synonyms: chloro(bromo)(2,4,6-triisopropylphenyl)phosphane
• CAS NO: 150331-74-1
• Molecular Weight: 349.678
• Mol File: 150331-74-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: chloro(bromo)(2,4,6-triisopropylphenyl)phosphane(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(bromo)(2,4,6-triisopropylphenyl)phosphane(150331-74-1)
• EPA Substance Registry System: chloro(bromo)(2,4,6-triisopropylphenyl)phosphane(150331-74-1)

Safety Data

• Hazardous Substances Data: 150331-74-1(Hazardous Substances Data)

Upstream product

• 53356-73-3 dichloro(2,4,6-tri-isopropylphenyl)phosphane 
• 87437-11-4 dibromo(2,4,6-triisopropylphenyl)phosphane 
• 21524-34-5 2,4,6-triisopropyl-1-bromobenzene 

Downstream Products

• 112790-12-2 tris(2,4,6-triisopropylphenyl)triphosphirane 
• 83466-54-0 Bis(2,4,6-tri-tert-butylphenyl)diphosphen 
• 87437-16-9 (E)-1-(2,4,6-triisopropylphenyl)-2-(2,4,6-tri-tert-butylphenyl)diphosphene 

Relevant articles and documents

Phosphine-catalysed reductive coupling of dihalophosphanes

Classically tetraaryl diphosphanes have been synthesized through Wurtz-type reductive coupling of halophosphanes R2PX or more recently, through the dehydrocoupling of phosphines R2PH. Catalytic variants of the dehydrocoupling reactio

The 1,1-carboboration of bis(alkynyl)phosphanes as a route to phosphole compounds

Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3-borylphospholes through a twofold 1,1-carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki-Miyaura type cross-coupling reactions (see scheme).