150370-06-2

Basic information

• Product Name: 1-(4-methoxy-2,6-dimethylphenyl)-2-phenyldiazene
• Synonyms: 1-(4-methoxy-2,6-dimethylphenyl)-2-phenyldiazene
• CAS NO: 150370-06-2
• Molecular Weight: 240.305
• Mol File: 150370-06-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxy-2,6-dimethylphenyl)-2-phenyldiazene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxy-2,6-dimethylphenyl)-2-phenyldiazene(150370-06-2)
• EPA Substance Registry System: 1-(4-methoxy-2,6-dimethylphenyl)-2-phenyldiazene(150370-06-2)

Safety Data

• Hazardous Substances Data: 150370-06-2(Hazardous Substances Data)

Upstream product

• 34743-49-2 4-methoxy-2,6-dimethylaniline 
• 586-96-9 Nitrosobenzene 
• 1778-71-8 3,5-Dimethyl-4-phenylazo-phenol 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 854053-65-9 2,6-dimethyl-[1,4]benzoquinone-4-(4-methoxy-2,6-dimethyl-phenylimine) 
• 34743-49-2 4-methoxy-2,6-dimethylaniline 

Relevant articles and documents

I2-Mediated 2: H -indazole synthesis via halogen-bond-assisted benzyl C-H functionalization

I2-Mediated benzyl C-H functionalization has been developed for the synthesis of 2H-indazoles, which features high efficiency, simple conditions and no need for metals. Mechanistic experiments and DFT calculations have revealed halogen bond assistance and a radical chain process for this reaction. The azo group and the bound iodine cooperate in the hydrogen abstraction step, which circumvents the thermodynamic disfavor of direct hydrogen abstraction by a simple iodine radical.