1504-14-9Relevant articles and documents
ALKALINE ISOMERIZATION OF PHENYLHYDRAZONES TO ALKYLPHENYLDIIMIDES
Kuznetsov, M.A.,Suvorov, A.A.
, p. 1684 - 1691 (2007/10/02)
When solutions pf phenylhydrazones in tri- or tetraethylene glycol are heated in the presence of the corresponding sodium glycolate, they undergo isomerization to alkylphenyldiimidates.There is a marked decrease in the isomerization rate in the transition from the hydrazones of aldehydes to the hydrazones of ketones.With the phenylhydrazones of ketones the reaction takes place almost unambiguously, but in the case of hydrazones of aldehydes it is complicated to an appreciable extent by side processes such as indolization and aminonitrile cleavage.