15052-09-2

Basic information

• Product Name: Naphthalene, 2-(1-methylethoxy)- (9CI)
• Synonyms: Naphthalene, 2-(1-methylethoxy)- (9CI)
• CAS NO: 15052-09-2
• Molecular Formula: C₁₃H₁₄O
• Molecular Weight: 186.24966
• Product Categories: NAPHTALENE
• Mol File: 15052-09-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 293°Cat760mmHg
• Flash Point: 113.5°C
• Appearance: /
• Density: 1.029g/cm³
• Vapor Pressure: 0.0031mmHg at 25°C
• Refractive Index: 1.577
• CAS DataBase Reference: Naphthalene, 2-(1-methylethoxy)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 2-(1-methylethoxy)- (9CI)(15052-09-2)
• EPA Substance Registry System: Naphthalene, 2-(1-methylethoxy)- (9CI)(15052-09-2)

Safety Data

• Hazardous Substances Data: 15052-09-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H14O/c1-10(2)14-13-8-7-11-5-3-4-6-12(11)9-13/h3-10H,1-2H3

Upstream product

• 75-30-9 2-iodo-propane 
• 875-83-2 sodium 2-naphtholate 
• 135-19-3 β-naphthol 
• 926-06-7 isopropyl methanesulfonate 
• 75-26-3 isopropyl bromide 
• 580-13-2 2-bromonaphthalene 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 91-20-3 naphthalene 
• 885-24-5 2-iso-Propoxynaphthalin-1-carbaldehyd 
• 612-94-2 2-phenylnaphthalene 
• 791088-70-5 1-bromo-2-(propan-2-yloxy)naphthalene 
• 135-19-3 β-naphthol 
• 91-57-6 2-Methylnaphthalene 
• 59115-49-0 2-(p-tolyl)naphthalene 
• 580-13-2 2-bromonaphthalene 
• 91-58-7 2-chloronaphthalene 

Relevant articles and documents

Cross-Coupling Reactions of Aryl Halides with Primary and Secondary Aliphatic Alcohols Catalyzed by an O,N,N-Coordinated Nickel Complex

A synthesis of alkyl aryl ethers was achieved via the cross-coupling of aryl halides with primary and secondary aliphatic alcohols catalyzed by a bench-stable nickel complex supported by a monoanionic O,N,N-tridentate ligand. This nickel-catalyzed reaction proceeds smoothly in the absence of a phosphine ligand, affording alkyl aryl ethers in moderate to good yields. (Figure presented.).

Nickel-catalyzed alkynylation of anisoles via C-O bond cleavage

A new cross-coupling reaction has been developed for the introduction of an alkyne moiety to an anisole derivative through C-O bond activation using an NHC ligand. This method has been used for direct alkynylation of a broad range of anisole derivatives a

Is the Hoveyda-Grubbs complex a vinylogous fischer-type carbene? Aromaticity-controlled activity of ruthenium metathesis catalysts

Three naphthalene-based analogues (4a-c) of the Hoveyda-Grubbs metathesis catalyst exhibited immense differences in reactivity. Systematic structural and spectroscopic studies revealed that the ruthenafurane ring present in all 2-isopropoxyarylidene chelates possesses some aromatic character, which inhibits catalyst activity. This aromatic stabilization within the chelate ring may be controlled by variation of the polycyclic core topology as was demonstrated for tetraline and phenanthrene derivatives (4d,e). General conclusions about a new mode of ligand-structure tuning in catalytic systems are presented.