150545-04-3Relevant articles and documents
Mild C - H halogenation of anilides and the isolation of an unusual palladium(I)-palladium(II) species
Bedford, Robin B.,Haddow, Mairi F.,Mitchell, Charlotte J.,Webster, Ruth L.
, p. 5524 - 5527 (2011/07/31)
Reducing the load: A facile palladium-catalyzed ortho-selective bromination and chlorination of anilides occurs under aerobic conditions at room temperature when N-halosuccinimides (NXS) are used in the presence of p-toluenesulfonic acid (PTSA). The orthopalladated PTSA complex is not only catalytically competent but also undergoes a reductive process to yield an unusual PdI-PdII tetramer (see structure; Pdgreen, Ored, Syellow, Cgray). Copyright
Solvent free catalytic C-H functionalisation
Bedford, Robin B.,Mitchell, Charlotte J.,Webster, Ruth L.
scheme or table, p. 3095 - 3097 (2010/08/04)
Solvent-free reaction conditions facilitate a range of aromatic C-H functionalisations that traditionally require acidic or disfavoured solvents. These reactions include selective ortho- and meta-arylation of aryl carbamates and anilides and selective halogenation reactions. The Royal Society of Chemistry 2010.
A Practical Ortholithiathion-Based Synthesis of 2-Chloro-6-methylaniline
Mulhern, Thomas A.,Davis, Mark,Krikke, James J.,Thomas, James A.
, p. 5537 - 5540 (2007/10/02)
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