150638-80-5

Basic information

• Product Name: N-isopropyl-2,6,6-trimethyl-2-cyclohexene-1-carboximidoyl chloride
• Synonyms: N-isopropyl-2,6,6-trimethyl-2-cyclohexene-1-carboximidoyl chloride
• CAS NO: 150638-80-5
• Molecular Weight: 227.777
• Mol File: 150638-80-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-isopropyl-2,6,6-trimethyl-2-cyclohexene-1-carboximidoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: N-isopropyl-2,6,6-trimethyl-2-cyclohexene-1-carboximidoyl chloride(150638-80-5)
• EPA Substance Registry System: N-isopropyl-2,6,6-trimethyl-2-cyclohexene-1-carboximidoyl chloride(150638-80-5)

Safety Data

• Hazardous Substances Data: 150638-80-5(Hazardous Substances Data)

Upstream product

• 564-24-9 (+/-)-α-cyclogeranic acid 
• 61899-99-8 2,6,6-trimethyl-2-hexene-1-carbonyl chloride 
• 4698-08-2 (E)-geranic acid 

Relevant articles and documents

HETEROCUMULENES IN ACYLATION REACTIONS. 1. MECHANISM OF ACID HYDROLYSIS OF 2,6,6-TRIMETHYL-1-CARBONYLCYCLOHEX-2-ENE AND ITS THIO AND N-ISOPROPYLIMINO ANALOGS

It was established that γ-protonation of the substrate takes place preferentially during the acid hydrolysis of 2,6,6-trimethyl-1-carbonylcyclohex-2-ene and its thio and N-isopropylimino analogs.The contribution from γ-protonation increases with increase in the polarity of the medium, the activity of H+, and the electronegativity of the heteroatom.The experimental results were confirmed by theoretical calculations (MNDO).