15067-64-8

Basic information

• Product Name: 2,4-bis(methylsulfanyl)-6-phenyl-1,3,5-triazine
• Synonyms: 1,3,5-Triazine, 2,4-bis(methylthio)-6-phenyl-; 2,4-Bis(methylsulfanyl)-6-phenyl-1,3,5-triazine; 2,4-BIS(METHYLTHIO)-6-PHENYL-S-TRIAZINE
• CAS NO: 15067-64-8
• Molecular Formula: C₁₁H₁₁N₃S₂
• Molecular Weight: 249.3551
• Mol File: 15067-64-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 471.7°C at 760 mmHg
• Flash Point: 239.1°C
• Density: 1.31g/cm³
• Vapor Pressure: 1.29E-08mmHg at 25°C
• Refractive Index: 1.663
• CAS DataBase Reference: 2,4-bis(methylsulfanyl)-6-phenyl-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-bis(methylsulfanyl)-6-phenyl-1,3,5-triazine(15067-64-8)
• EPA Substance Registry System: 2,4-bis(methylsulfanyl)-6-phenyl-1,3,5-triazine(15067-64-8)

Safety Data

• Hazardous Substances Data: 15067-64-8(Hazardous Substances Data)

Upstream product

• 30886-13-6 6-phenyl-1H-[1,3,5]triazine-2,4-dithione 
• 74-88-4 methyl iodide 
• 15998-30-8 4-methylthio-6-phenyl-1,3,5-triazin-2(1H)-thione 
• 2227-79-4 benzenecarbothioamide 
• 21406-30-4 N-Benzoylamino-dithiokohlensaeuremethylester 

Downstream Products

• 1722-18-5 2-phenyl-1,3,5-triazine 
• 34752-99-3 2-methylthio-4-phenyl-6-phenylamino-1,3,5-triazine 

Relevant articles and documents

Synthesis of 1,3,5-triazine derivatives by the reaction of S,S '-dimethyl N-cyanocarbonimidodithioate with amides

S ,S '-Dimethyl N-cyanocarbonimidodithioate (1) reacted with amides (2) in the presence of sodium hydride in a mixture of benzene and N,N-dimethylacetamide to give the corresponding N-acyl-N'-carbamoyl-S-methylisothioureas (3). Refluxing of 3 in methanol gave the corresponding cyclized product, 1,3,5-triazin-2(1H)-one derivatives (4). Compounds (4) were found to be useful intermediates for the synthesis of trisubstituted 1,3,5-triazines.

Reactions with N-Acylimino-dithiocarbonic-acid-diesters

Reactions of N-acylimino-dithiocarbonic-acid-S,S-diesters 1 with nucleophilic compounds present new possibilities to synthesize heterocycles.With amines 1a reacts by mono- and disubstitution, respectively, of methylthio-groups to isothioureas 2 and guanidines 3, with 1,2-binucleophilic arenes to benzoheterocycles 4, with aliphatic diamines to imidazolines 5, pyrimidines 6, diazepines 7 and the hexamethylene-diamine-derivatives 8. 1a reacts also with hydrazines to 1,2,4-triazoles 9 and with hydrazides to the thiosemicarbazones 10 or 1,3,4-oxadiazoles 11.Heterocyclisations of 1 with guanidines, thiourea, salts of thiourea and amidines give the 1,3,5-triazines 12, 14, 15 and 16.N-benzoyl-dithiocarbonic-acid-methylester -amid reacts with CH-acidic compounds to thiazoles 17.The structures of the final products are determined by i.r.-, 1H-n.m.r.-, u.v.- and mass-spectras.