15081-74-0

Basic information

• Product Name: Cyclohexanol, 2-[bis(methylthio)methylene]-
• CAS NO: 15081-74-0
• Molecular Formula: C9H16OS2
• Molecular Weight: 204.357
• Mol File: 15081-74-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-[bis(methylthio)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-[bis(methylthio)methylene]-(15081-74-0)
• EPA Substance Registry System: Cyclohexanol, 2-[bis(methylthio)methylene]-(15081-74-0)

Safety Data

• Hazardous Substances Data: 15081-74-0(Hazardous Substances Data)

Upstream product

• 17649-90-0 2-(bis-methylsulfanyl-methylene)-cyclohexanone 

Downstream Products

• 18448-47-0 methyl cyclohex-1-ene-1-carboxylate 
• 5828-09-1 S-Methyl cyclohexene-1-thiocarboxylate 
• 15089-10-8 1--2-(methylthio)cyclohexane 
• 636-82-8 cyclohexene-1-carboxylic acid 

Relevant articles and documents

1,3-Carbonyl transposition methodology employing α-oxo ketene dithioacetals: Application in the synthesis of phenols and (±)-myodesmone

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α-OXOKETENE DITHIOACETALS: VERSATILE SUBSTRATES FOR 1,3-CARBONYL TRANSPOSITIONS

A two step procedure for the conversion of α-oxoketene dithioacetals to β-substituted α,β-unsaturated thioesters or acids is described.The overall transformation represents a 1,3-carbonyl transposition in which the original ketone carbonyl emerges as the carbonyl of an acid or thioester.The resulting thioesters and acids constitute versatile acylating reagents in accord with established procedures.