15096-10-3

Basic information

• Product Name: Methyl 2,2-diphenylethenyl sulfide
• Synonyms: 1,1'-[(Methylthio)ethenylidene]bisbenzene;Methyl 2,2-diphenylethenyl sulfide
• CAS NO: 15096-10-3
• Molecular Formula: C₁₅H₁₄S
• Molecular Weight: 226.34
• Mol File: 15096-10-3.mol
• Article Data: 14

Chemical Properties

• Melting Point: 74.0-74.5 °C(Solv: ethanol (64-17-5))
• Boiling Point: 115-120 °C
• Appearance: /
• Density: 1.073±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Methyl 2,2-diphenylethenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,2-diphenylethenyl sulfide(15096-10-3)
• EPA Substance Registry System: Methyl 2,2-diphenylethenyl sulfide(15096-10-3)

Safety Data

• Hazardous Substances Data: 15096-10-3(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 13882-12-7 S-methyl methanethiosulfinate 
• 119-61-9 benzophenone 
• 28460-01-7 diethyl 1-(methylthio)methylphosphonate 
• 1779-54-0 methylthiomethyl(triphenyl)phosphonium chloride 
• 624-92-0 Dimethyldisulphide 
• 67341-86-0 Ph₂CCHHgBr 
• 536-74-3 phenylacetylene 
• 100-53-8 phenylmethanethiol 
• 506-68-3 bromocyane 
• 33703-57-0 2-methylthiomethyl-1,1-diphenylethanol 
• 67-68-5 dimethyl sulfoxide 
• 108-86-1 bromobenzene 
• 599-67-7 1,1-diphenylethanol 

Downstream Products

• 142407-31-6 (S)-(-)-methyl-(2,2-diphenyl) vinyl sulfoxide 
• 21147-11-5 C₁₅H₁₄OS 
• 120677-76-1 (2,2-diphenyl)ethenyltriphenylgermane 

Relevant articles and documents

1,1-Diphenyl-2-methylsulfinyl ethanol: A model compound to study the reactivity towards CNBr of a photoadduct of methionine on CγH2

The photoadduct formed by photolysis of the [Bapa0, (pBzl)Phe5, Met(O2)11]SP/NK-1 complex localised within the T173MP175 domain of the NK-1 receptor cannot be cleaved by CNBr on the C-side of methionine; an unusual rearrangement of the intermediate sulfonium instead occurred. The reactivity of 1,1-diphenyl-2-methylsulfinyl ethanol 10 towards CNBr treatment and the stability of the 1,1-diphenyl oxirane 14 were analysed by NMR and mass spectrometry. 1,1-Diphenyl ethylene 13 can be formed from epoxide 14 even in slightly acidic conditions and during positive DCI/NH3 mass spectrometry analysis. Altogether, these results suggest that if a covalent linkage between the [Bapa0, (pBzl)Phe5, Met(O2)11] and the NK-1 receptor occurred on the CγH2 of methionine-174, CNBr treatment will lead to an epoxide/ketone and an ethylenic compound.

Sodium iodide-mediated synthesis of vinyl sulfides and vinyl sulfones with solvent-controlled chemical selectivity

Vinyl sulfides and vinyl sulfones are ubiquitous structures in organic chemistry because of their presence in natural and biologically active compounds and are very frequently encountered structural motifs in organic synthesis. Herein we report an efficie

Preparation method of distyrene thioether compounds

The invention discloses a preparation method of distyrene thioether compounds. The preparation method includes following steps: dispersing 1, 1-distyrene, aryl/alkyl sodium sulfinate and acidic reductant into a solvent, and allowing coupling reaction to obtain the distyrene thioether compound. The preparation method can systematically synthesize a series of the distyrene thioether compounds and isneedless of adopting a transitional metal catalyst, simple in reaction system, wide in substrate application range, high in yield, easy-to-obtain in reaction raw material, low in cost and little in pollution.