15104-47-9Relevant articles and documents
Phosphonate monoesters as carboxylate-like linkers for metal organic frameworks
Iremonger, Simon S.,Liang, Junmei,Vaidhyanathan, Ramanathan,Martens, Isaac,Shimizu, George K. H.,Daff, Thomas D.,Aghaji, Mohammad Zein,Yeganegi, Saeid,Woo, Tom K.
, p. 20048 - 20051 (2011)
Bidentate phosphonate monoesters are analogues of popular dicarboxylate linkers in MOFs, but with an alkoxy tether close to the coordinating site. Herein, we report 3-D MOF materials based upon phosphonate monoester linkers. Cu(1,4-benzenediphosphonate bis(monoalkyl ester), CuBDPR, with an ethyl tether is nonporous; however, the methyl tether generates an isomorphous framework that is porous and captures CO2 with a high isosteric heat of adsorption of 45 kJ mol-1. Computational modeling reveals that the CO 2 uptake is extremely sensitive both to the flexing of the structure and to the orientation of the alkyl tether.
A mild electroassisted synthesis of (hetero)arylphosphonates
Sengmany, Stéphane,Ollivier, Anthony,Le Gall, Erwan,Léonel, Eric
supporting information, p. 4495 - 4500 (2018/06/29)
The electrochemically-assisted synthesis of (hetero)arylphosphonates from (hetero)aryl halides and dimethyl phosphite is described. Very mild and simple conditions are employed as the cross-coupling is carried out in galvanostatic mode, in an undivided ce
