15111-96-3

Basic information

• Product Name: DIHYDRO CUMINYL ACETATE
• Synonyms: DIHYDRO CUMINYL ACETATE;FEMA 3561;(S)-PERILLYL ACETATE;PERILLA ACETATE;(4-Isopropenyl-1-cyclohexen-1-yl)methyl acetate;1-Cyclohexene-1-methanol, 4-(1-methylethenyl)-, acetate;1-Cyclohexene-1-methanol,4-(1-methylethenyl)-,acetate;4-(1-methylethenyl)-1-cyclohexene-1-methanoacetate
• CAS NO: 15111-96-3
• Molecular Formula: C₁₂H₁₈O₂
• Molecular Weight: 194.27
• EINECS: 239-162-4
• Mol File: 15111-96-3.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 258.4°Cat760mmHg
• Flash Point: 98.9°C
• Appearance: /
• Density: 0.967g/cm³
• Vapor Pressure: 0.0138mmHg at 25°C
• Refractive Index: 1.473
• CAS DataBase Reference: DIHYDRO CUMINYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIHYDRO CUMINYL ACETATE(15111-96-3)
• EPA Substance Registry System: DIHYDRO CUMINYL ACETATE(15111-96-3)

Safety Data

• Hazardous Substances Data: 15111-96-3(Hazardous Substances Data)

Usage

Description

DIHYDRO CUMINYL ACETATE, also known as p-Mentha-1,8-dien-7-yl-acetate, is a naturally occurring compound found in various citrus fruits such as tangerine, orange, bitter orange, and lemon peel oils, as well as bergamot oil and grapefruit juice. It is characterized by its warm herbaceous spicy odor and is known for its distinctive fragrance.

Uses

Used in Flavor and Fragrance Industry:
DIHYDRO CUMINYL ACETATE is used as a flavoring agent for its warm herbaceous spicy odor, adding a unique and pleasant taste to various food and beverage products.
DIHYDRO CUMINYL ACETATE is also used as a fragrance ingredient in the perfumery industry, where its distinctive scent is utilized to create captivating and long-lasting fragrances for personal care products, such as perfumes, colognes, and body lotions.
Used in Aromatherapy:
In the field of aromatherapy, DIHYDRO CUMINYL ACETATE is used for its potential therapeutic benefits. Its warm and spicy aroma is believed to have calming and relaxing effects, making it a popular choice for use in massage oils, candles, and diffusers to promote a sense of well-being and reduce stress.
Used in Cosmetics and Personal Care Products:
DIHYDRO CUMINYL ACETATE is used as a key ingredient in the formulation of cosmetics and personal care products, such as lotions, creams, and shampoos, due to its pleasant scent and potential skin-conditioning properties. Its inclusion in these products can enhance the sensory experience for the user and contribute to a more enjoyable and effective product.

InChI:InChI=1/C12H18O2/c1-9(2)12-6-4-11(5-7-12)8-14-10(3)13/h4,12H,1,5-8H2,2-3H3

Upstream product

• 36203-31-3 [(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl acetate 
• 64-19-7 acetic acid 
• 138-86-3 limonene. 
• 108-24-7 acetic anhydride 
• 23516-38-3 β-pinene trans-epoxide 
• 28252-26-8 trans-2-methylene-5-isopropenyl-cyclohexyl acetate 
• 6931-54-0 β-pinene oxide 
• 536-59-4 perillol 
• 56246-58-3 β-pinene oxide 
• 536-59-4 (-)-perillyl alcohol 
• 64-18-6 formic acid 
• 875-08-1 (-)-β-Pinenoxid 
• 5989-54-8 (-)-(S)-limonene 
• 18031-40-8 (S)-(-)-perillaldehyde 

Downstream Products

• 536-59-4 (-)-perillyl alcohol 
• 130860-49-0 (2R,4S)-2--4-isopropenyl-1-methylenecyclohexane 
• 130860-50-3 (4S)-4-isopropenyl-1-<2',2-bis(methoxycarbonyl)ethyl>cyclohexene 
• 58940-31-1 6-Oxo-p-mentha-1,8-dien-7-yl acetat 
• 58940-38-8 3-Oxo-p-mentha-1,8-dien-7-yl acetat 
• 18031-40-8 (S)-(-)-perillaldehyde 
• 61585-35-1 p-menth-1-ene 
• 99-82-1 Menthane 
• 1002120-13-9 [4-(propan-2-yl)cyclohexen-1-yl]methyl acetate 
• 46337-76-2 [4-(propane-2-yl)cyclohexyl]methyl acetate 
• 536-59-4 perillol 
• 1637633-34-1 C₂₁H₃₀N₂O 

Relevant articles and documents

Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

Heteropoly acid catalysts for the synthesis of fragrance compounds from bio-renewables: Acetylation of nopol and terpenic alcohols

The cesium salt of tungstophosphoric heteropoly acid, Cs2.5H0.5PW12O40, is an active and environmentally friendly heterogeneous catalyst for the liquid-phase acetylation of nopol and several biomass-derived terpenic alcohols (i.e., α-terpineol, nerol, geraniol, linalool, menthol, isoborneol, perillyl alcohol, carveol, isopulegol, carvacrol and nerolidol) with acetic anhydride. The resulting flavor and fragrance acetic esters, which are widely used in perfumery, household and food products, are obtained in good to excellent yields. The reactions occur at room temperature with low catalyst loadings without substantial catalyst leaching and can be performed with stoichiometric amounts of an acetylating agent in solvent free systems.

Synthesis of (+)-perillyl alcohol from (+)-limonene

(+)-Perillyl alcohol (1) has been synthesised in four steps and 39% overall yield from commercially available limonene oxide (4). The sequence features, as its key step, a palladium(0)-mediated transformation of a secondary allylic acetate (6) into its primary isomer (7). An application of (+)-perillyl alcohol (1) in a formal synthesis of naturally occurring (-)-mesembrine (2) and (-)-mesembranol was demonstrated.