151237-08-0Relevant articles and documents
Palladium(ii) N-heterocyclic allenylidene complexes with extended intercationic Pd?Pd interactions and MMLCT phosphorescence
Zou, Chao,Lin, Jinqiang,Suo, Sa,Xie, Mo,Chang, Xiaoyong,Lu, Wei
, p. 5319 - 5322 (2018)
Extended intercationic Pd?Pd contacts of 3.30 ? in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd(ii) N-heterocyclic allenylidene complexes. The Pd
An electron-deficient tris(triazole)-based discotic liquid crystal that exhibits fast electron transport
Bala, Indu,De, Joydip,Dhingra, Shallu,Gupta, Santosh Prasad,Pal, Santanu Kumar,Pandey, Upendra Kumar
supporting information, p. 5628 - 5632 (2021/05/17)
In this study, a C3-symmetric star-shaped discotic mesogen has been reported based on an electron-deficient tris(triazole) central rigid core functionalized with three peripheral trialkoxyphenyl units. The mesogen exhibits an enantiotropic columnar hexagonal (Colh) phase that can sustain over a significant temperature range. When used in space-charge limited current (SCLC) devices, it showed ambipolar charge transport behavior with high electron mobility (μe) of 1.61 × 10-2 cm2 V-1 s-1 at ambient temperature. The finding is sufficiently significant to warrant their use in organic electronic devices.
Modular synthesis of polymers containing 2,5-di(thiophenyl)-N-arylpyrrole
Truong, Tran N. B.,Savagatrup, Suchol,Jeon, Intak,Swager, Timothy M.
, p. 1133 - 1139 (2018/03/27)
A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility.