15131-31-4

Basic information

• Product Name: {RuCl₂(CO)2(C₆H₅CH₂NH₂)2}
• CAS NO: 15131-31-4
• Molecular Weight: 442.307
• Mol File: 15131-31-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {RuCl₂(CO)2(C₆H₅CH₂NH₂)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {RuCl₂(CO)2(C₆H₅CH₂NH₂)2}(15131-31-4)
• EPA Substance Registry System: {RuCl₂(CO)2(C₆H₅CH₂NH₂)2}(15131-31-4)

Safety Data

• Hazardous Substances Data: 15131-31-4(Hazardous Substances Data)

Upstream product

• 14898-67-0 ruthenium(III) chloride trihydrate 
• 201230-82-2 carbon monoxide 
• 100-46-9 benzylamine 
• 14898-67-0 ruthenium trichloride hydrate 

Relevant articles and documents

Ruthenate(VI)-catalysed dehydrogenation of primary amines to nitriles, and crystal structures of cis-2*0.5MeOH and cis-2*CH2Cl2

Catalytic dehydrogenation of benzylic and other primary amines RCH2NH2 to the corresponding nitriles RCN by the system trans-2-/S2O82- has been investigated.The complex cis-2+ and the new cis-2+ (R = o-, m- or p-ClC6H4, o-MeC6H4, o- or p-MeOC6H4); cis-2+ (R = Ph or p-MeOC6H4) and cis-2+ have been made, and dehydrogenation of the co-ordinated amine in the ruthenium complexes to the corresponding nitriles in cis-2+ (L-L = bipy or phen) by peroxodisulfate demonstrated.The crystal structures of cis-*0.5MeOH and cis-2*CH2Cl2, the latter a product of co-ordinated amine dehydrogenation by peroxodisulfate to give cis-2+, were determined.Raman, infrared and 1H NMR data for the complexes have been measured; the latter suggest that the cis configurations of the amine complexes are retained in solution.