151408-92-3

Basic information

• Product Name: 2,2-dimethyl-5-<2-(1,3-dioxa-2-cyclohexyl)ethyl>cyclohexan-1-one
• Synonyms: 2,2-dimethyl-5-<2-(1,3-dioxa-2-cyclohexyl)ethyl>cyclohexan-1-one
• CAS NO: 151408-92-3
• Molecular Weight: 240.343
• Mol File: 151408-92-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-dimethyl-5-<2-(1,3-dioxa-2-cyclohexyl)ethyl>cyclohexan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethyl-5-<2-(1,3-dioxa-2-cyclohexyl)ethyl>cyclohexan-1-one(151408-92-3)
• EPA Substance Registry System: 2,2-dimethyl-5-<2-(1,3-dioxa-2-cyclohexyl)ethyl>cyclohexan-1-one(151408-92-3)

Safety Data

• Hazardous Substances Data: 151408-92-3(Hazardous Substances Data)

Upstream product

• 33884-43-4 2-(2-Bromoethyl)-1,3-dioxane 
• 6553-64-6 6,6-Dimethyl-2-cyclohexen-1-one 

Relevant articles and documents

Synthesis of polycyclic cyclobutane derivatives by tandem intramolecular Michael-aldol reaction under two complementary conditions: TBDMSOTf-Et3N and TMSI-(TMS)2NH

The treatment of αβ-unsaturated esters having a ketone function at an appropriate position with either TBDMSOTf in the presence of Et3N or TMSI in the presence of (TMS)2NH provided, via a tandem intramolecular Michael-aldol reaction sequence, several different types of cyclobutane derivatives. The two reaction conditions were complementary. Tricyclo[4.2.1.03,8]nonanes 34 and 55, tricyclo[5.1.104,8]nonane 40, tricyclo[5.4.0.03,7]undecane 51, tetracyclo[5.4.0.03,7.09,11]undecane 45, and the bicyclo[3.2.0]heptanes 56, 57, and 58, which have structures either partially or completely similar to those of endiandric acids A (1a), B (1b), and C (2), trihydroxydecipiadiene (3), lintenone (4), italicene (5), and filifolone (6), were stereoselectively synthesized by the tandem reaction.