1516899-85-6

Basic information

• Product Name: C₅₂H₅₂O₁₀
• CAS NO: 1516899-85-6
• Molecular Weight: 836.979
• Mol File: 1516899-85-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅₂H₅₂O₁₀(CAS DataBase Reference)
• NIST Chemistry Reference: C₅₂H₅₂O₁₀(1516899-85-6)
• EPA Substance Registry System: C₅₂H₅₂O₁₀(1516899-85-6)

Safety Data

• Hazardous Substances Data: 1516899-85-6(Hazardous Substances Data)

Upstream product

• 143406-35-3 25,27-dihydroxy-26,28-dipropoxycalix[4]arene 
• 1516899-81-2 C₃₈H₄₂Br₂O₄ 
• 1516899-83-4 C₅₈H₆₀O₁₀ 

Relevant articles and documents

Novel chiral (salen)Mn(iii) complexes containing a calix[4]arene unit in 1,3-alternate conformation as catalysts for enantioselective epoxidation reactions of (Z)-aryl alkenes

Two new chiral calix[4]arene-salen ligands 1a,b, based on calix[4]arene platforms in 1,3-alternate conformation, have been prepared by a new general synthetic pathway. Their Mn(iii) complexes, 3a,b, have shown fairly good efficiency in the asymmetric epoxidation of styrene and substituted styrenes, whereas excellent catalytic activity and selectivity were observed with rigid bicyclic alkenes, namely 1,2-dihydro-naphthalene and substituted 2,2′-dimethyl-chromene. The higher catalytic properties of 3a may be ascribed to the more rigid and inherently chiral structure as proved by molecular modelling, NMR spectroscopy and X-ray data of the similarly structured UO2 complexes 2a,b.