1516900-23-4Relevant articles and documents
Biotinylated metathesis catalysts: Synthesis and performance in ring closing metathesis
Kajetanowicz, Anna,Chatterjee, Anamitra,Reuter, Raphael,Ward, Thomas R.
, p. 373 - 379 (2014/06/24)
Nine biotinylated Grubbs-Hoveyda and Grubbs-type metathesis catalysts were synthesized and evaluated in ring closing metathesis reactions of N-tosyl diallylamine and 5-hydroxy-2-vinylphenyl acrylate. Their catalytic activity in organic-and aqueous solvents was compared with the second generation Grubbs-Hoveyda catalyst. The position of the biotin-moiety on the N-heterocyclic carbene was found to critically influence the catalytic activity of the corresponding ruthenium-based catalysts. Springer Science+Business Media New York 2013.