15189-06-7

Basic information

• Product Name: {Ni(CO)(C₆H₉O₃P)3}
• Synonyms: {Ni(CO)(C₆H₉O₃P)3}
• CAS NO: 15189-06-7
• Molecular Weight: 567.029
• Mol File: 15189-06-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {Ni(CO)(C₆H₉O₃P)3}(CAS DataBase Reference)
• NIST Chemistry Reference: {Ni(CO)(C₆H₉O₃P)3}(15189-06-7)
• EPA Substance Registry System: {Ni(CO)(C₆H₉O₃P)3}(15189-06-7)

Safety Data

• Hazardous Substances Data: 15189-06-7(Hazardous Substances Data)

Upstream product

• 281-33-4 2,8,9-trioxa-1-phospha-adamantane 
• 13463-39-3 tetracarbonyl nickel 

Relevant articles and documents

Transition metal complexes of a constrained phosphite ester. V. Metal carbonyl complexes of 2,8,9-trioxa-1-phosphaadamantane

The preparation and characterization of metal carbonyl complexes of 2,8,9-trioxa-1-phosphaadamantane, P(OCH)3(CH2)3, are described. Substitution products obtained from Ni(CO)4 include compounds of the type Ni(CO)4-x[P(OCH)3(CH2)3]x where x = 1, 2, 3, or 4. Synthesis of the mono- and disubstituted complexes of Fe(CO)5, Cr(CO)6, Mo(CO)6, and W(CO)6 with P(OCH)3(CH2)3 is also reported. A study of the carbonyl infrared stretching frequencies implies that P(OCH)3(CH2)3 is equal to other phosphites in π-bonding ability. The proton nmr spectra of the compounds are discussed with special attention given to the disubstituted complexes. The proton nmr spectra of analogous disubstituted complexes of P(OCH2)3CCH3 discussed previously by us (see ref 5) are more rigorously treated.