1519-40-0

Basic information

• Product Name: Benzene, 1-[(R)-ethylsulfinyl]-4-methyl-
• CAS NO: 1519-40-0
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 1519-40-0.mol
• Article Data: 45

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(R)-ethylsulfinyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(R)-ethylsulfinyl]-4-methyl-(1519-40-0)
• EPA Substance Registry System: Benzene, 1-[(R)-ethylsulfinyl]-4-methyl-(1519-40-0)

Safety Data

• Hazardous Substances Data: 1519-40-0(Hazardous Substances Data)

Upstream product

• 622-63-9 ethyl p-tolyl sulfide 
• 227949-78-2 (S)-diethyl (ethylsulfinyl)methylphosphonate 
• 925-90-6 ethylmagnesium bromide 
• 116386-53-9 (-)-(R_S,R)-1-chloro-2-phenylethyl p-tolyl sulfoxide 
• 82079-38-7 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranosyl (+)-(R)-p-toluenesulfinate 
• 144539-55-9 (+)-(S)-1-bromovinyl-p-tolyl sulfoxide 
• 100-52-7 benzaldehyde 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 64809-18-3 4-benzyloxy-3-methylbutyronitrile 
• 74-88-4 methyl iodide 
• 79378-71-5 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranosyl (-)-(S)-p-toluenesulfinate 
• 122406-32-0 [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-phenyl-amine 
• 116386-54-0 (-)-1-chloroundecyl p-tolyl sulfoxide 
• 1517-82-4 (-)-(S)-O-menthyl p-toluenesulfinate 

Downstream Products

• 105259-63-0 1-Methyl-4-((S)-1-phenylselanyl-ethanesulfinyl)-benzene 
• 124568-01-0 (-)-3S,R_S-1-fluoro-3-<(4-methylphenyl)sulphinyl>-2-butanone 
• 115879-02-2 (+)-3R,R_S-1-fluoro-3-<(4-methylphenyl)sulphinyl>-2-butanone 
• 308818-87-3 (R_S)-1-hydroxy-1-phenyl-2-(p-tolylsulfinyl)propane 
• 308818-89-5 (R_S)-3-hydroxy-2-(p-tolylsulfinyl)butane 
• 31350-93-3 (S_S)-1-chloroethyl (4-methylphenyl) sulfoxide 
• 31350-93-3 (-)-(R)-1-chloroethyl p-tolyl sulfoxide 
• 223392-43-6 (R_S)-1-chloroethyl (4-methylphenyl) sulfoxide 
• 100907-36-6 (R)-2-Methylene-4-((R)-toluene-4-sulfinyl)-pentanoic acid 
• 100907-22-0 (S)-2-Methylene-4-((R)-toluene-4-sulfinyl)-pentanoic acid 
• 84736-73-2 1-(N-t-butyl-N-hydroxylamino)-1-phenyl-prop-2-yl p-tolyl sulfoxide 
• 51774-51-7 (-)-(R)-S-Aethyl-S-(p-tolyl)-sulfoximin 

Relevant articles and documents

Highly Enantioselective Oxidation of Sulfides Mediated by a Chiral Titanium Complex

-

Enzymatic kinetic resolution of chiral sulfoxides-an enantiocomplementary approach

A new enzymatic assay for the preparation of chiral sulfoxides that is enantiocomplementary to the known (S)-enantiomer-reducing activity of methionine sulfoxide reductase A (MsrA) is described. To this end, we have utilized the enzyme DMSO reductase (DmsABC), recently discovered by us being highly upregulated in stationary phase E. coli bacteria.

Chemoenzymatic Deracemization of Chiral Sulfoxides

The highly enantioselective enzyme methionine sulfoxide reductase A was combined with an oxaziridine-type oxidant in a biphasic setup for the deracemization of chiral sulfoxides. Remarkably, high ee values were observed with a wide range of substrates, thus providing a practical route for the synthesis of enantiomerically pure sulfoxides.