152019-82-4

Basic information

• Product Name: 5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine
• Synonyms: 5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine
• CAS NO: 152019-82-4
• Molecular Weight: 299.372
• Mol File: 152019-82-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine(152019-82-4)
• EPA Substance Registry System: 5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine(152019-82-4)

Safety Data

• Hazardous Substances Data: 152019-82-4(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 256-96-2 dibenzoazepine 
• 56667-12-0 (Z)-2,2'-dibromostilbene 
• 104-94-9 4-methoxy-aniline 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 36901-75-4 (2-bromobenzyl)triphenylphosphonium bromide 

Relevant articles and documents

Palladium-Catalyzed N-Arylation of Iminodibenzyls and Iminostilbenes with Aryl- and Heteroaryl Halides

Compounds containing the iminodibenzyl and iminostilbene ring systems are prevalent in medicinal targets and functional materials. Herein, we report palladium-catalyzed conditions for the N-arylation of these ring systems. This protocol could be applied to a variety of (hetero)aryl chloride and bromide substrates, including ones, which are sterically hindered or those containing a variety of functional groups. Use of the fourth-generation palladacycle precatalyst gave good to excellent yields by using low palladium-catalyst loadings (0.1 to 1 mol %).