1522-67-4Relevant articles and documents
Studies on enamides. Part-5: A novel pathway for photochemical reaction of N-1-cyclohexenyl-N-phenylarylamides
Ghosh,Nandi,Saima
, p. 3169 - 3170 (1996)
The oxidative photolysis of N-1-cyclohexenyl-N-phenylarylamides has culminated in the photochemical synthesis of anilides by a novel reaction pathway.
Rhodium-Catalyzed Synthesis of Amides from Functionalized Blocked Isocyanates
Beauchemin, André M.,Derasp, Joshua S.
, p. 8104 - 8109 (2019/08/26)
Isocyanates are useful building blocks for the synthesis of amides, although their widespread use has been limited by their high reactivity, which often results in poor functional group tolerance and a propensity to oligomerize. Herein, a rhodium-catalyzed synthesis of amides is described coupling boroxines with blocked (masked) isocyanates. The success of the reaction hinges on the ability to form both the isocyanate and the organorhodium intermediates in situ. Relying on masked isocyanate precursors and on the high reactivity of the organorhodium intermediate results in broad functional group tolerance, including protic nucleophilic groups such as amines, anilines, and alcohols.
A metal-free and a solvent-free synthesis of thio-amides and amides: An efficient Friedel-Crafts arylation of isothiocyanates and isocyanates
Varun, Begur Vasanthkumar,Sood, Ankush,Prabhu, Kandikere Ramaiah
, p. 60798 - 60807 (2015/02/19)
A rapid, metal-free and solvent-free (very low loading of solvent in few cases) reaction conditions for synthesizing thioamides and amides using a Bronsted super acid such as triflic acid has been developed. This method shows a broad substrate scope with
Dithiocarbamate and DBU-promoted amide bond formation under microwave condition
Kumar, Katari Naresh,Sreeramamurthy, Kintali,Palle, Sadananda,Mukkanti, Khagga,Das, Parthasarathi
experimental part, p. 899 - 902 (2010/05/03)
Dithiocarbamate and DBU-promoted amide bond formation under microwave condition has been reported. The versatility of this synthetic protocol has been demonstrated with various carboxylic acids and different dithiocarbamates. The products thus obtained ha