15232-90-3Relevant articles and documents
Copper-catalyzed alkene arylation with diaryliodonium salts
Phipps, Robert J.,McMurray, Lindsay,Ritter, Stefanie,Duong, Hung A.,Gaunt, Matthew J.
supporting information; experimental part, p. 10773 - 10776 (2012/08/07)
Alkenes and arenes represent two classes of feedstock compounds whose union has fundamental importance to synthetic organic chemistry. We report a new approach to alkene arylation using diaryliodonium salts and Cu catalysis. Using a range of simple alkenes, we have shown that the product outcomes differ significantly from those commonly obtained by the Heck reaction. We have used these insights to develop a number of new tandem and cascade reactions that transform readily available alkenes into complex arylated products that may have broad applications in chemical synthesis.
Fluoride ion mediated intramolecular sulfenylation of α-silyl sulfones: Ramberg-Ba?cklund annulation to exocyclic fused olefins
Scarpetti, David,Fuchs, Philip L.
, p. 8084 - 8090 (2007/10/02)
A series of α-trimethylsilyl-substituted phenyl sulfones bearing an ω-p-toluenethiosulfonyl α-substituent were synthesized and subjected to treatment with tetra-n-butylammonium fluoride to provide the corresponding monocyclic sulfides (6-, 7-, and 8-membe
